Pressure swing adsorption
Pressure swing adsorption (PSA) is a technology used to separate some gas species from a mixture of gases under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at near-ambient temperatures and differs significantly from cryogenic distillation techniques of gas separation. Specific adsorptive materials (zeolites) are used as a trap, preferentially adsorbing the target gas species at high pressure. The process then swings to low pressure to desorb the adsorbed material.
Pressure swing adsorption processes rely on the fact that under high pressure, gases tend to be attracted to solid surfaces, or "adsorbed". The higher the pressure, the more gas is adsorbed; when the pressure is reduced, the gas is released, or desorbed. PSA processes can be used to separate gases in a mixture because different gases tend to be attracted to different solid surfaces more or less strongly. If a gas mixture such as air, for example, is passed under pressure through a vessel containing an adsorbent bed of zeolite that attracts nitrogen more strongly than it does oxygen, part or all of the nitrogen will stay in the bed, and the gas coming out of the vessel will be enriched in oxygen. When the bed reaches the end of its capacity to adsorb nitrogen, it can be regenerated by reducing the pressure, thereby releasing the adsorbed nitrogen. It is then ready for another cycle of producing oxygen-enriched air.
Using two adsorbent vessels allows near-continuous production of the target gas. It also permits so-called pressure equalisation, where the gas leaving the vessel being depressurised is used to partially pressurise the second vessel. This results in significant energy savings, and is common industrial practice.
Aside from their ability to discriminate between different gases, adsorbents for PSA systems are usually very porous materials chosen because of their large specific surface areas. Typical adsorbents are activated carbon, silica gel, alumina and zeolite. Though the gas adsorbed on these surfaces may consist of a layer only one or at most a few molecules thick, surface areas of several hundred square meters per gram enable the adsorption of a significant portion of the adsorbent's weight in gas. In addition to their selectivity for different gases, zeolites and some types of activated carbon called carbon molecular sieves may utilize their molecular sieve characteristics to exclude some gas molecules from their structure based on the size of the molecules, thereby restricting the ability of the larger molecules to be adsorbed.
PSA has also been discussed as a future alternative to the non-regenerable sorbent technology used in space suit Primary Life Support Systems, in order to save weight and extend the operating time of the suit.
Double Stage PSA
(DS-PSA, sometimes referred to as Dual Step PSA). With this variation of PSA developed for use in Laboratory Nitrogen Generators generation of nitrogen gas is divided into two steps: in the first step, the compressed air is forced to pass through a carbon molecular sieve to produce nitrogen at a purity of approximately 98%; in the second step this nitrogen is forced to pass into a second carbon molecular sieve and the nitrogen gas reaches a final purity up to 99.999%. The purge gas from the second step is recycled and partially used as feed gas in the first step.
In addition, the purge process is supported by active evacuation for better performance in the next cycle. The goals of both of these changes is to improve efficiency over a conventional PSA process.
The DS-PSA is also applied to up levels oxygen concentration in this case a zeolite aluminum silica based adsorb Nitrogen in the first stage focusing Oxygen 95%, and in the second stage the molecular sieve carbon-based adsorbs the residual nitrogen in a reverse cycle, concentrating to 99% oxygen.
Rapid pressure swing adsorption or RPSA is frequently used in portable oxygen concentrators. It allows a significant reduction in the size of the adsorbent bed when high purity is not essential and feed gas can be discarded. It works by quickly cycling the pressure while alternately venting opposite ends of the column at the same rate. This means that unadsorbed gases progress along the column much faster and are vented at the distal end, while adsorbed gases do not get the chance to progress and are vented at the proximal end.